Synthesis of thermally robust benzimidazolone-based wholly aromatic polyketones

An Alternative Method for Synthesis of Thermally Stable Aromatic Polyesters Containing Schiff Base Unites

In this paper, an efficient method for synthesis of aromatic polyesters containing schiff base units is described by preparation of two polyesters. These polyesters have been prepared by the reaction of terephthaloyl dichloride on Schiff bases derived from p-hydroxybenzyldehyde and 4,4-diamino diphenyl ether, 4,4-diamino diphenyl methane. The Polymers were characterized by IR, CHNS, thermal...

Asymmetric catalytic synthesis of polyketones and polycarbonates*

Two examples are presented for the synthesis of optically active polymers with main-chain chirality from achiral monomers using chiral metal-complexes as catalysts. Asymmetric alternating copolymerization of α-olefins with carbon monoxide provided optically active polyketones when catalyzed by an (R,S)-BINAPHOS–Pd complex. From propene and CO, highly isotactic polyketone with high enantioselect...

New Thermally Stable Aromatic Polyimides Based on Aromatic Diamine ‎2,5-Bis(3-amino-4-methyl benzene)-1,3,4-oxadiazole (BAMO):‎ Synthesis and Characterization

In current study, the synthesis and characterization of novel thermally stable polyimides (PIs) containing an 1,3,4-oxadiazole moiety based on a diamine, i.e. 2,5-bis(3-amino-4-methyl benzene)-1,3,4-oxadiazole (BAMO), have been reported. The polymers were characterized using FT-IR and elemental analysis (CHN). Thermal and mechanical behaviours of the prepared PIs were studied by thermo-gravimet...

an alternative method for synthesis of thermally stable aromatic polyesters containing schiff base unites

Polarized Emission of Wholly Aromatic Bio-Based Copolyesters of a Liquid Crystalline Nature

A novel thermotropic liquid crystalline polymers poly{3-benzylidene amino-4-hydroxybenzoic acid (3,4-BAHBA)-co-trans-4-hydroxycinnamic acid (4HCA: trans-coumaric acid)} (Poly(3,4-BAHBA-co-4HCA)), was synthesized by the thermal polycondensation of 4HCA and 3,4-BAHBA, which was synthesized by a reaction of 3-amino-4-hydroxybenzoic acid (3,4-AHBA) with benzaldehyde. When the 4HCA compositions of P...